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广州地化所SCI收录论文题录(2015.8.27-2015.9.29)

纤维素飞米纸具有质量轻、机械强度高、光学品质卓越、热牢固性好、热延展性低、隔断性高以至可生物分解等一层层优点,在电子构件、突显基板、太阳能电池、包装隔断材料等世界具备光辉的利用潜在的能量。可是,CNP对水敏感,大批量的水或高湿度意况会使三磷酸腺苷润胀,从而变成其失去原本的平稳和教条强度,那大大约束了CNP在水中以致高湿条件下的运用。近来,国际上相同接收乙酰化、硅烷化或接枝改性等方法来改革CNP的抗水品质,那么些点子在早晚水准上能够改正CNP的耐水性,但复杂的化学改性方法也会不可幸免地促成CNP机械品质的损失和筹备花费的滋长。 近年来,中国科高校马那瓜生物质资源源与进程商讨所生物基本材料质组群木质生物素精炼课题组,采取了易回笼的有机酸水解法从自然木质纤维中领取含红萝卜素的飞米纤维素,然后通过机械力协作效应制得具备能够抗水品质的CNP。整个制备进程没有须求任何复杂的化学改性,直接通过一步法有机酸水解分级解离天然纤维原料,并收获含纤维素的微米藻多糖;随后在二四十烷乙酰胺中,通过机械力成效达成飞米纤维表面分子的局地溶解,溶解的果胶分子在干燥成膜的历程中发生重结晶;重结晶的木质素分子和具有自然疏水性子的乙酰胆碱同盟效应抵补了CNP中微米胡萝卜素之间的欠缺,形成越发留意的微米构造。该方法律制度得的CNP具备卓绝的教条品质(255 MPa, 19.7 MJ m-3),不仅克服了CNP怕水的缺点(湿强可达83 MPa,为现有文献报道的最高值),而且木质素的引入还赋予了CNP优异的紫外吸收性能。该研究开发的制备过程无需复杂工艺和昂贵试剂,所用溶剂均可回收,整个过程清洁,并可实现CNP强度和紫外屏蔽性能的可控制备,产品具有良好的应用前景。相关成果作为Back cover文章发表在*Journal of Materials Chemistry A* 杂志上(*JMCA* 2018,DOI: 10.1039/C8TA01986J)。

先是形成单位诗歌13篇:

飞米木质素因其独特的构造及优惠的习性一向饱受学术和集团界的青睐和珍贵,日渐产生新资料和维生素科学领域的研商热门。不过,从纯天然木质淀粉中领取皮米纤维素的工艺进程一贯留存着能耗高、用水量大、化学药品不易回笼等主题材料。为夺取上述难题,木质纤维精炼课题组短期从事于付出新型浅绿急迅的皮米三磷酸腺苷制备方法,在国际上先是树立了根据易回笼的固体酸和有机酸水解法律制度备皮米血红蛋白的法子连串,包涵磷钨酸水解法律制度备果胶微米晶体CNC(Carbohydrate Polymers, 二〇一六, 110: 415),甲酸水解-TEMPO氧化法律制度备高分散性CNC(Carbohydrate Polymers, 2014, 113: 605),氯化物催化的甲酸水解法律制度备CNC(Cellulose, 二〇一四, 23: 2389)和甲状腺素皮米纤丝CNF(Industrial Crops and Products, 2015, 94: 736),以至一步法从烟秆中提取具有高抗水性子的CNF(Journal of Materials Chemistry A, 2018),并前后相继申请一多级中黄炎子孙民共和国发明专利,前段时间已授权2项(ZL2011104830736;ZL201510680481.X)。课题组在皮米木质素方面包车型客车连带类别研讨为神速、低本钱、铁锈色制备飞米木质素以致有关高质量复合材质开拓和行业化的利用提供了新的思路,相关成果综述发表在《化学进展》(Progress in Chemistry, 2018, 30, 448)杂志上,并被引入为热门作品。

1.Gao, Bo; Du, Xueqing; Wang, Xinming; Tang, Jianhui; Ding, Xiang; Zhang, Yanli; Bi, Xinhui; Zhang, Gan. Parent, Alkylated, and Sulfur/Oxygen-Containing Polycyclic Aromatic Hydrocarbons in Mainstream Smoke from 13 Brands of Chinese Cigarettes. ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2015, 49: 9012-9019. DOI: 10.1021/acs.est.5b01108

相关类别研讨获得了国家自然科学基金、国家十七五科技(science and technology卡塔尔支撑安顿、莱茵河省重大研究开发陈设、江苏省自然科学基金等的扶助。

2.Shen, R. -Q.; Ding, X.; He, Q. -F.; Cong, Z. -Y.; Yu, Q. -Q.; Wang, X. -M. Seasonal variation of secondary organic aerosol tracers in Central Tibetan Plateau. ATMOSPHERIC CHEMISTRY AND PHYSICS, 2015, 15: 8781-8793. DOI: 10.5194/acp-15-8781-2015

有关成果宣布:

3.Liu, T.; Wang, X.; Deng, W.; Hu, Q.; Ding, X.; Zhang, Y.; He, Q.; Zhang, Z.; Lu, S.; Bi, X.; Chen, J.; Yu, J.. Secondary organic aerosol formation from photochemical aging of light-duty gasoline vehicle exhausts in a smog chamber. ATMOSPHERIC CHEMISTRY AND PHYSICS, 2015, 15: 9049-9062. DOI: 10.5194/acp-15-9049-2015

  1. Qingbo Wang, Haishun Du, Fang Zhang, Yuedong Zhang, Meiyan Wu, Guang Yu, Chao Liu*, Bin Li*, Hui Peng. Flexible cellulose nanopaper with high wet tensile strength, high toughness and tunable ultraviolet blocking ability fabricated from tobacco stalk via a sustainable method. Journal of Materials Chemistry A, 2018, DOI:10.1039/C8TA01986J.

  2. 杜海顺, 刘超, 张苗苗, 孔庆山, 李滨*, 咸漠. 飞米木质素的制备及行当化, 化学进展, 2018, 30, 448-462.

  3. Haishun Du, Chao Liu, Yuedong Zhang, Guang Yu, Chuanling Si*, Bin Li*. Preparation and characterization of functional cellulose nanofibrils via formic acid hydrolysis pretreatment and the followed high-pressure homogenization. Industrial Crops and Products, 2016, 94, 736-745.

  4. Haishun Du, Chao Liu, Xindong Mu, Wenbo Gong, Dong Lv, Yimei Hong, Chuanling Si*, Bin Li*. Preparation and characterization of thermally stable cellulose nanocrystals via a sustainable approach of FeCl3-catalyzed formic acid hydrolysis. Cellulose, 2016, 23, 2389-2407.

  5. Chao Liu#, Bin Li#, Haishun Du, Wenbo Gong, Dong Lv, Xindong Mu*, Hui Peng*. Properties of nanocellulose isolated from corncob residue using sulfuric acid, formic acid, oxidative and mechanical methods. Carbohydrate Polymers, 2016, 151, 716-724.

  6. Bin Li, Wenyang Xu, Dennis Kronlund, Anni M??tt?nen, Jun Liu, Jan-Henrik Sm?tt, Jouko Peltonen, Stefan Willf?r, Xindong Mu, Chunlin Xu. Cellulose nanocrystals prepared via formic acid hydrolysis followed by TEMPO-mediated oxidation. Carbohydrate Polymers, 2015, 133, 605-612.

  7. Yefei Liu, Haisong Wang, Guang Yu, Qingxue Yu, Bin Li*, Xindong Mu*. A novel approach for the preparation of nanocrystalline cellulose by using phosphotungstic acid. Carbohydrate Polymers, 2014, 110, 415-422.

  8. 一种制备飞米生物素的方法. 中华夏族民共和国发明专利, 专利号: 2012104830736.(授权日:2017-06-06)

  9. 一种金属盐催化甲酸水解制备飞米三磷酸腺苷的方法. 中国表明专利. 专利号: 二零一四10680481.X.(授权日:2017-07-04)

4.Hu, Jianfang; Zhou, Haoda; Peng, Ping'an; Yang, Xiaoqiang; Spiro, Baruch; Jia, Guodong; Wei, Gangjian; Ouyang, Tingping. Reconstruction of a paleotemperature record from 0.3-3.7 ka for subtropical South China using lacustrine branched GDGTs from Huguangyan Maar. PALAEOGEOGRAPHY PALAEOCLIMATOLOGY PALAEOECOLOGY, 2015, 435: 167-176. DOI: 10.1016/j.palaeo.2015.06.014

图片 1

5.Lu, Hong; Shen, Chenchen; Zhang, Zhirong; Liu, Ming; Sheng, Guoying; Peng, Ping'an; Hsu, Chang Samuel. 2,3,6-/2,3,4-Aryl lsoprenoids in Paleocene Crude Oils from Chinese Jianghan Basin: Constrained by Water Column Stratification. ENERGY & FUELS, 2015, 29: 4690-4700. DOI: 10.1021/acs.energyfuels.5b00110

一步法皮米纤维素——二十七烷乙酰胺中表面分子溶解——重结晶——获得致密飞米布局泛酸微米纸

6.Yao, Jun-Ming; Chen, Hua-Yong; Tian, Yang-Chao; Song, Wei-Le; Zhu, San-Yuan. Three-dimensional imaging of a single fluid inclusion in sphalerite by nano X-ray tomography. ORE GEOLOGY REVIEWS, 2015, 71: 116-120. DOI: 10.1016/j.oregeorev.2015.05.008

图片 2

7.Wu, Chao; Chen, Huayong; Hollings, Pete; Xu, Deru; Liang, Pei; Han, Jinsheng; Xiao, Bing; Cai, Keda; Liu, Zhenjiang; Qi, Yukun. Magmatic sequences in the Halasu Cu Belt, NW China: Trigger for the Paleozoic porphyry Cu mineralization in the Chinese Altay-East Junggar. ORE GEOLOGY REVIEWS, 2015, 71: 373-404. DOI: 10.1016/j.oregeorev.2015.06.017

圣何塞财富所制备出高湿强、高韧性兼具紫外屏蔽作用的氨基酸微米纸

8.Zeng, Xiangying; Liu, Zhiyang; He, Lixiong; Cao, Shuxia; Song, Han; Yu, Zhiqiang; Sheng, Guoying; Fu, Jiamo. The occurrence and removal of organophosphate ester flame retardants/plasticizers in a municipal wastewater treatment plant in the Pearl River Delta, China. JOURNAL OF ENVIRONMENTAL SCIENCE AND HEALTH PART A-TOXIC/HAZARDOUS SUBSTANCES & ENVIRONMENTAL ENGINEERING, 2015, 50: 1291-1297. DOI: 10.1080/10934529.2015.1055158

9.Feng, Junxi; Chen, Duofu. Characterization of authigenic carbonates from Huoshaogang landfill, Guangzhou, China: implication for microbial metabolism. ENVIRONMENTAL EARTH SCIENCES, 2015, 74: 4839-4851. DOI: 10.1007/s12665-015-4485-5

10.Zhang, Dongliang; Huang, Guangqing; Yin, Xiaoling; Gong, Qinghua. Residents' Waste Separation Behaviors at the Source: Using SEM with the Theory of Planned Behavior in Guangzhou, China. INTERNATIONAL JOURNAL OF ENVIRONMENTAL RESEARCH AND PUBLIC HEALTH, 2015, 12: 9475-9491. DOI: 10.3390/ijerph120809475

11.Liu, Tengyu; Wang, Xinming; Deng, Wei; Zhang, Yanli; Chu, Biwu; Ding, Xiang; Hu, Qihou; He, Hong; Hao, Jiming. Role of ammonia in forming secondary aerosols from gasoline vehicle exhaust. SCIENCE CHINA-CHEMISTRY, 2015, 58: 1377-1384. DOI: 10.1007/s11426-015-5414-x